How can I use Item Level Targeting to specify Windows Virtual Desktops (WVD) Multi-session Windows?

The query you want is:

Step 1 – The Operating System is Windows 10

Step 2 – and the WMI Query:select * from Win32_OperatingSystem, where OperatingSystemSKU = 175

The result will look like this:

NOTE: For other unusual SKUs and information on how to get the ID, see the Microsoft article on OperatingSystemSKU Enum.